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Two-Phase Heat Transfer ​

Nucleation superheat ​

Phase change: liquid -> gas / gas -> liquid

  • Homogeneous nucleation 均匀成核 (A-B')
  • Heterogeneous nucleation 异相成核 (A-B-C-D)

Specific volume = density−1

Temperature-volume relation

Clausius-Clapeyron relation [final-term] ​

Mechanical equilibrium:

(pb−pl)πr∗2=σ2πr∗ or Δp=pb−pl=2σr∗
  • pb: Internal pressure in bubble
  • pl: Pressure outside the bubble
  • r∗: radius of bubble
  • σ: coefficient of surface tension 表面张力

Clausius-Clapeyron relation b/w psat & Tsat (where hfg is Latent heat of phase change 相变潜热 / enthalpy of vaporization):

The Clausius-Clapeyron equation specifies the temperature dependencies of pressure, most importantly, vapor pressure, at a discontinuous phase transition b/w two phase of matter of a single contituent

(dpdT)sat =hfgTsat (νg−νf)→νg≫νf Saturated vapor dpgdTg=hfgTg(νg)→pgνg=RTgdpgpg=hfgRTg2dTgln⁡(pbpl)=−hfgR(1Tb−1Tsat )Tb−Tsat =RTbTsat hfgln⁡(pbpl)→Tsat : Saturation temperature at plTb: Saturation temperature at pbTb−Tsat =RTbTsat hfgln⁡(1+2σplr∗)

Superheat (=Tb−Tsat  ) required to maintain a bubble

when 2σ/plr∗≪1,pb≃pl.RTb/pb=νb≃νfg .

Tb−Tsat ≃RTbTsat2σhfgpbr∗≃2σTsat νfghfg(1r∗)pl≪pc

where pc is Critical pressure.

Superheat for homogeneous nucleation of water at p=0.1MPa:220∘C

Heterogeneous nucleation: dissolved gas & microcavities at surface

Pool boiling ​

  • Boiling curve: Heat-transfer regime of pool boiling
  • Critical heat flux: Linked with onset of pool fluidization (suspension of liquid by vapor stream)

Hydrodynamic instability:

  • Kelvin- Helmholtz instability: 2 fluid flow counterpart: critical heat flux =...
qcr′′=ρghfgjg=C1ρghfg[σ(ρf−ρg)gρg2]1/4

where C1=0.13.

pressure-Critical heat flux relation

Flow boiling ​

  • Heat transfer regime: Mass flow rate, fluids, geometry, heat flux magnitude and distribution
  • Dry-out type CHF: High quality
  • DNB (departure from nucleate boiling) type CHF (similar to CHF in pool boiling): Low quality

Enthalpy 焓 [J/kg] at z from inlet [core]:

h=hl,in+4qw″zDG

where:

  • qw″: heat flux
  • z: height w.r.t. the inlet
  • D: diameter of pipe
  • G=ρg⟨jg⟩+ρf⟨jf⟩=ρmvm: mass flux

4qw″zDG comes from

  1. The area of pipe wall: zπD
  2. The whole heat: ΔQ=qw″⋅zπD
  3. The enthalpy increase: ΔQ/W=ΔQ/(G⋅πD2/4)=4qw″zDG

definition: Thermal equilibrium

Two physical systems are in thermal equilibrium if there is no net flow of thermal energy between them when they are connected by a path permeable to heat (From wikipedia)

definition: Thermal equilibrium quality

Thermal equilibrium quality: ratio of the actual enthalpy of a fluid mixture to the enthalpy if it were completely vaporized, assuming the mixture is in thermal equilibrium at the local pressure.

Thermal equilibrium quality at z from inlet [core]:

xeq=h−hl,sathfg=hl,in+4qw″zDG−hl,sathfg
  • hl,sat: Saturated enthalpy
  • hfg: enthalpy of vaporization
  • When h=hfg+hl,sat,xeq=1

For boiling curve:

  • single-phase flow: q″=h(Tw−Tsat)
  • The corner: (Tw−Tsat)m−1
  • 2-phase flow: q″=h(Tw−Tsat)m,m≃3

Subcooled boiling ​

Stages of void fraction
  1. Region I: Subcooled nucleate boiling (Onset of nucleate boiling (核态沸腾起始点), ZNB: mean or bulk temperature below Tsat)
  2. Region II: Subcooled nucleate boiling (Onset of significant void (显着空洞), ZD)
  3. Region III: Saturated boiling (xeq=0: since liquid does not reach saturation condition due to the bubble presence and non-equilibrium)
  4. Region IV: Saturated boiling (thermal equilibrium condition at ZE)
  • For ZD, that's Saha-Zuber correlation to determine
  • For the curve: profile-fit method

Net vapor generation (Bubble departure) ​

Net vapor generation: The point at which bubbles can depart from the wall before they suffer condensation (ZD)

在流体中,蒸汽的“产生”速度开始大于“凝结”速度,从而出现净增的蒸汽

  • Thermally controlled departure: The wall heat flux is balanced by heat removal due to liquid subcooling at ZD.
  • Hydrodynamically controlled departure: The bubble detachment is primarily the result of drag (or shear) force overcoming the surface tension force

Saha-Zuber correlation: (empirical)

At first, introduce Peclet number [core]:

St=NuRePr∼Pe=NuSt⟹=GDnCpfkf

where:

  • Cpf: Saturated liquid isobaric heat capacity
  • kf: Saturated liquid thermal conductivity
no usexeq(ZD)={−0.0022q″DncpfkfhfgPe≤70000−153.85q″GhfgPe≥70000

For temperature:

Tsat−TD={0.0022q″DnkfPe≤70000153.85q″GcplPe≥70000

and ZD is calculated as:

ZD=πDh24GCpl(TD−Tin)πDhqw′′=DhGCpl(TD−Tin)4qw′′
  • 分子:将总质量流量的流体从 Tin 显热加热到 TD 所需要的总功率
  • 分母:单位长度加热功率
Saha-Zuber correlation

Subcooled flow quality and void fraction ​

Profile-fit approach: Currently accepted approach for determining the flow quality in subcooled region [core]

x(z)=xeq(z)−xeq(ZD)exp⁡[xeq(z)xeq(ZD)−1]

The flow quality x(z):

  • =0 at ZD
  • approaches xeq(z) asymptotically as z increases
  • When xeq(z)=0,x(z)=−1exeq(ZD)≈−0.368xeq(ZD)

For quality:

x≠xeq
  • well-saturated boiling flow:
x≈xeq
  • Subcooled boiling flow:
x≥0,xeq<0

Using profile-fit approach to obtain xeq How to determine ZD: Profile-fit method

pump →

Mission: prediction of void fraction for heat transfer, etc.

  1. To predict the void fraction ⟨α⟩, the Drift-flux model is used (need ⟨x⟩)

Drift-flux model:

⟨α⟩=⟨jg⟩C0(⟨jg⟩+⟨jf⟩)+⟨⟨vfg⟩⟩

where

⟨jg⟩=G⟨xf⟩ρg,⟨jf⟩=G(1−⟨xf⟩)ρf

and xf is the flow quality

  • For HEM, ⟨α⟩=⟨jg⟩/(⟨jg⟩+⟨jf⟩) and 20% overprediction
  1. Distribution parameter C0 and drift velocity ⟨⟨vfg⟩⟩ can be obtained by formulas in the last chapter
  2. To obtain the flow quality ⟨xf⟩, Profile-fit approach (xf∼xeq) and OSV model (onset of significant void) are used (need xeq(z),xeq(ZD))
    1. To obtain xeq, Thermal equilibrium quality is used
    2. To obtain xeq(ZD), the Saha-Zuber correlation is used

Saturated Cooling ​

Heat transfer:

  • 1ϕ:q″=h1ϕ(Tw−Tbulk)
    • Nu=h1ϕDkf where kf is the thermal conductivity
    • Dittus-Boelton equation for 1ϕ convective heat transfer (Turbulent flow):Nu=0.023Re0.8Prm,m=0.3(cooling),0.4(heating)
    • Re=ρfjfD/μf where jf=G(1−x)/ρf
  • 2ϕ:q″=h2ϕ(Tw−Tsat) (Saturated boiling flow)
    • h2ϕ=hNB⏟nucleate boiling+hC⏟forced convective flow(Chen correlation)

Boling incipience ​

Fourier's law:

q″=−kl∂T∂r∼klTb−Tsatr∗

Clausius-Clapeyron relation:

Tw=Tsat+2σTsatvfghfg1r∗.

Thus

q″=klhfg8σTsatvfg(Tw−Tsat)2.

Quiz3 ​

Water is injected with a velocity of 1.5 m/s into a uniformly heated vertical pipe with a diameter of 0.05 m and length of 10 m receiving a heat flux of 5×106 W/m2. Inlet pressure and temperature of water are 4.64 MPa and 25∘C. Saturation temperature, Tsat, at 4.64 MPa is 259∘C. Saturated liquid enthalpy, hl,sat, and enthalpy of vaporization, hfg, are 1132 kJ/kg and 1665 kJ/kg. Saturated liquid density and saturated steam density are 785 kg/m3 and 23.4 kg/m3. Enthalpy of water at 4.64 MPa and 25∘C is 123 kJ/kg. Density of the saturated liquid can be used as a good estimation of density of subcooled water. Other average fluid properties are Cpl=4980 J/kg⋅K,kl=0.570 W/m⋅K, μl=9.4×10−5 kg/(m⋅s). Surface tension at the saturation pressure can be used approximately for the calculation (σ=0.0329 N/m).

  1. Calculate the mixture mass flux (unit in kg/m2s). In the uniformly heated pipe:
G=ρl,invl,in=785×1.5 kg/m2s=1177.5 kg/m2s.

1119−1236

  1. Calculate the enthalpy at 4 m from the pipe inlet (unit in kJ/kg).
h=hl,in+4qw″zDG=(123+4×5×103×40.05×1177.5) kJ/kg≈1481.811 kJ/kg.

1407−1555

  1. Calculate the thermal equilibrium quality located at the 4 m from the pipe inlet. Thermal equilibrium quality is calculated as
xe(z)|z=4=h(z)|z=4−hl,sathfg=1481.811−11321665≈0.210.

0.2

  1. Calculate the Peclet number for the inlet liquid.
Pe=GCplDkl=1177.5×4980×0.050.570≈5.143816×105

488680−540120

  1. Calculate the temperature for onset of significant void, TD, (unit in K). According to Saha-Zuber correlation, when Pe>70000:
Tsat−TD=153.85q″GCpl=153.85×5×1061177.5×4980 K≈131.183 K

Thus TD≈Tsat−131.3 K≈(259+273.15−131.183) K≈400.967 K

381−421

  1. Calculate the length at which onset of significant void occurs, ZD, (unit in m).
ZD=πDh24GCpl(TD−Tin)πDhqw′′=DhGCpl(TD−Tin)4qw′′≈1.507 m.

1.43−1.59

  1. Calculate the equilibrium quality at ZD,xe(ZD).
Based on Saha-Zuber correlation, when Pe>70000: (Not right while using this formula)xe(ZD)=−153.85q″Ghfg=−153.85×5×1061177.5×1665×103≈−0.392.
h|z=ZD=hl,in+4qw″ZDDG≈(123+4×5×103×1.5070.05×1177.5) kJ/kg≈634.392 kJ/kgxe(ZD)=h|z=ZD−hl,sathfg≈−0.299.

−0.313−−0.283

  1. Calculate the quality at Z=2 m,x(Z=2 m). The quality is calculated based on the profile-fit approach:
x(z)|z=2 m=xe(z)|z=2 m−xe(ZD)exp⁡[xe(z)|z=2 mxe(ZD)−1]

where

xe(z)|z=2 m=hl,in+4q″z|z=2 mGD−hl,sathfg≈−0.198

Thus

(Wrong answer in 7th leads to wrong answer here)x(z)|z=2 m≈−0.198−(−0.392)×exp⁡[−0.198−0.392−1]≈0.0411
x(z)|z=2 m≈−0.198−(−0.299)×exp⁡[−0.198−0.299−1]≈0.0153.

0.0143−0.0158

  1. Calculate the distribution parameter, C0, at Z=2 m. Given:
C0=β[1+(1/β−1)b]b=(ρg/ρf)0.1β=(x/ρg)/(x/ρg+(1−x)/ρf)

According to the given formula:

Wrong answerβ≈0.041123.4/(0.041123.4+1−0.0411785)≈0.590b=(23.4/785)0.1≈0.704C0≈0.590×[1+(1/0.590−1)0.704]≈1.047
β≈0.015323.4/(0.015323.4+1−0.0153785)≈0.342b=(23.4/785)0.1≈0.704C0≈0.342×[1+(1/0.342−1)0.704]≈0.884

0.837−0.925

  1. Calculate the void fraction at Z=2 m,α(Z=2 m).

The void fraction is calculated by

⟨α⟩=⟨jg⟩C0⟨j⟩+⟨⟨vgj⟩⟩

where

Wrong answerjg=Gxρg≈1177.5×0.041123.4 m/s≈2.068 m/sjf=G(1−x)ρf≈1177.5×(1−0.0411)785 m/s≈1.438 m/sj=jg+jf≈(2.068+1.438) m/s≈3.507 m/s.
jg=Gxρg≈1177.5×0.15323.4 m/s≈0.769 m/sjf=G(1−x)ρf≈1177.5×(1−0.153)785 m/s≈1.477 m/sj=jg+jf≈(0.769+1.477) m/s≈2.246 m/s⟨⟨vgj⟩⟩=2.9(Δρgσρf2)0.25=2.9×[(785−23.4)×9.8×0.03297852]0.25 m/s≈0.410 m/s.

Thus

Wrong answer⟨α⟩≈0.7690.884×2.246+0.410≈0.507.
⟨α⟩≈2.0681.047×3.507+0.410≈0.321.

0.302−0.334

Quiz4 ​

Liquid water with the mass flux (G) of 2000 kg/m2/s is injected into a uniformly heated vertical pipe at pressure ( P ) condition of 15.5 MPa and inlet temperature ( T ) of 300∘C. The pipe has the diameter (Dh) of 0.05 m and height of 15 m . It is heated by the heat source through the outside wall with a heat flux (qw′′) of 8×105 W/m2.

Key information are given below:

  • Mass flux: G=2000 kg/(m2⋅s);
  • Pressure condition: P=15.5MPa;
  • Inlet temperature condition: Tin =300∘C;
  • Saturation temperature: Tsat =345∘C;
  • Liquid enthalpy at inlet: hin=1338 kJ/kg;
  • Saturated liquid enthalpy: hsat,f=1623 kJ/kg;
  • Saturated gas enthalpy: hsat,g=2599 kJ/kg;
  • Latent heat: hfg=976 kJ/kg;
  • Saturated liquid density: ρf=598 kg/m3;
  • Saturated liquid dynamic viscosity: μf=6.88×10−5 Pa⋅ s;
  • Saturated liquid thermal conductivity: kf=0.452 W/m/K;
  • Saturated liquid isobaric heat capacity: Cpf=8.74 kJ/kg/K;
  • Saturated gas density: ρg=101 kg/m3;
  • Saturated gas dynamic viscosity: μg=2.31×10−5 Pa⋅ s;
  • Steam-water surface tension: σ=0.0047N/m;
  • Steel-water contact angle: ϕs=38∘.

Assumptions: (1) Ignore the pressure loss in two-phase mixing section. (2) Air and water fluid compressibility is negligible. (3) Water properties change with temperature is negligible.

  1. Assume that water properties do not vary significantly in single-phase flow section. Calculate the liquid convective heat transfer coefficient using the Dittus-Boelter equation.
Nuf=0.023Ref0.8Prf0.4Ref=(GDh)/μfPrf=(Cpfμf)/kfNuf=(hfDh)/kf

The answer of hf should be given in W/(m2K).

Answer:

Nuf=0.023Ref0.8Prf0.4=0.023(GDhμf)0.8(Cpfμfkf)0.4=hfDhkf⟹hf=0.023kfDh(GDhμf)0.8(Cpfμfkf)0.4≈1.98340×104 W/(m2⋅K).

18810−20790

  1. What is the temperature difference between the wall temperature and mean bulk liquid temperature (wall super heat [∘C])?
qx″=hΔT

The answer of ΔT should be given in ∘C.

Answer:

qw″=hfΔT⟹ΔT=qw″hf≈40.335∘C.

38.4−42.4

  1. Determine the temperature for the onset of nucleate boiling, TONB, using Basu et al. (2004) correlation.
ΔTONB=2F(ϕs)(σTsatqw″ρghfgkf)0.5

where

F(ϕs)=1−exp⁡[−(πϕs180)3−0.5(πϕs180)],ϕs=38∘

Tsat in the correlation should be used in the unit K. The answer of TONB should be given in ∘C.

Answer:

ΔTONB=TONB−Tsat=2F(ϕs)(σTsatqw″ρghfgkf)0.5⟹TONB=Tsat+2F(ϕs)(σTsatqw″ρghfgkf)0.5

where

F(ϕs)|ϕs=38∘=1−exp⁡[−(πϕs180)3−0.5(πϕs180)]≈0.464.

Thus

TONB≈345.696∘C.

329−363

  1. Calculate the temperature of significant void, TD.
Pe=(GDhCpf)/kfTsat−TD=0.0022((qw′′Dh)/kf),Pe<7×104Tsat−TD=154(qw′′GCpf),Pe>7×104

The answer of TD should be given in ∘C.

Answer:

Pe=(GDhCpf)/kf≈1.9336283×106.

Thus

Tsat−TD=154(qw′′GCpf)⟹TD=Tsat−154(qw′′GCpf)≈337.952∘C.

321−355

  1. Calculate the length for the onset of significant void, ZD.
ZD=πDh24GCpf(TD−Tin)πDhqw′′

The answer of ZD should be given in m .

Answer:

ZD=πDh24GCpf(TD−Tin)πDhqw′′=DhGCpf(TD−Tin)4qw′′≈10.366 m.

9.88−10.9

  1. In another scenario, assume that the heat flux is unknown and the wall temperature is fixed at 370∘C. Chen's correlation is used to calculate two-phase heat transfer coefficient and heat flux at x=0.2. Saturation pressure at 370∘C is 21.0 MPa . Calculate the nucleate boiling heat transfer coefficient in Chen's correlation hNB.
hNB=S×0.00122[(k0.79Cp0.45ρ0.49)fσ0.5μf0.29hfg0.24ρg0.24]ΔTsat0.24ΔP0.75

where

S=11+2.53×10−6Re1.17Re=RefF1.25Ref=G(1−x)DhμfF=1 for 1Xtt<0.1F=2.35(0.213+1Xtt)0.736 for 1Xtt>0.1Xtt=(1−xx)0.9(ρgρf)0.5(μfμg)0.1ΔTsat=Tw−TsatΔP=P(Tw)−P(Tsat)

The answer of hNB should be given in W/(m2 K).

Answer:

ΔTsat=Tw−Tsat=(370−345)∘C=25∘CΔP=P(Tw)−P(Tsat)=(21.0−15.5) MPa=5.5×106 PaXtt|x=0.2=(1−xx)0.9(ρgρf)0.5(μfμg)0.1|x=0.2≈1.596⟹1Xtt≈0.617>0.1⟹F=2.35(0.213+1Xtt)0.736≈2.066Ref=G(1−x)Dhμf≈1.163×106⟹Re=RefF1.25≈2.880×106⟹S=11+2.53×10−6Re1.17≈0.0108⟹hNB=S×0.00122[(k0.79Cp0.45ρ0.49)fσ0.5μf0.29hfg0.24ρg0.24]ΔTsat0.24ΔP0.75≈6700.441 W/(m2⋅K).

6407−7081

  1. Calculate the convective boiling heat transfer coefficient in Chen's correlation hc. Flow conditions are the same as in Question 6.
hc=0.023Ref0.8Prf0.4kfDhF

The answer of hc should be given in W/(m2 K).

Answer:

hc=0.023Ref0.8Prf0.4kfDhF≈34279.827 W/(m2⋅K).

32395−35805

  1. Calculate the total boiling heat transfer coefficient in Chen's correlation h2ϕ.
h2ϕ=hNB+hc

The answer of h2ϕ should be given in W/(m2 K).

Answer:

h2ϕ=hNB+hc≈40980.268 W/(m2⋅K).

38760−42840

  1. Calculate the saturation boiling heat flux using Chen's correlation and temperature given in Question 6.
qw′′=h2Φ(Tw−Tsat)

The answer of qw′′ should be given in W/m2.

Answer:

qw′′=h2Φ(Tw−Tsat)=h2Φ(370−345) K≈1024506.694 W/m2.

969000−1071000

  1. Assume that the liquid velocity is zero (pool conditions), calculate the critical heat flux using Zuber's correlation:
qcr′′=ρgjghfg

where the vapor velocity leading to the onset of fluidization jg is given by:

jg=0.13[σ(ρf−ρg)gρg2]1/4

The answer of qcr′′ should be given in W/m2.

Answer:

jg=0.13[σ(ρf−ρg)gρg2]1/4≈0.0283 m/s⟹qcr′′=ρgjghfg≈2789163.270 W/m2.

2650500−2929500

Released under the MIT License.